{"id":15525,"date":"2025-12-31T14:38:47","date_gmt":"2025-12-31T14:38:47","guid":{"rendered":"https:\/\/www.hnjournal.net\/?page_id=15525"},"modified":"2025-12-31T14:38:49","modified_gmt":"2025-12-31T14:38:49","slug":"7-1-32","status":"publish","type":"page","link":"https:\/\/www.hnjournal.net\/ar\/7-1-32\/","title":{"rendered":""},"content":{"rendered":"<div class=\"journal-article\" style=\"margin-bottom: 20px;\"><h3 style='text-align: left; font-family:Times New Roman;'>Studying the Mechanism of Soot Reduction via Co-Combustion of Methane in a Laminar n-heptane Diffusion Flame<\/h3><h4 style='text-align: right; font-family:Simplified Arabic;'>\u062f\u0631\u0627\u0633\u0629 \u0622\u0644\u064a\u0629 \u062a\u0642\u0644\u064a\u0644 \u062a\u0643\u0648\u0651\u0646 \u0627\u0644\u0633\u0646\u0627\u062c \u0645\u0646 \u062e\u0644\u0627\u0644 \u0627\u0644\u0627\u062d\u062a\u0631\u0627\u0642 \u0627\u0644\u0645\u0634\u062a\u0631\u0643 \u0644\u0644\u0645\u064a\u062b\u0627\u0646 \u0641\u064a \u0644\u0647\u0628 \u0627\u0646\u062a\u0634\u0627\u0631 \u0635\u0641\u062d\u064a \u0644\u063a\u0627\u0632 n-\u0647\u064a\u0628\u062a\u0627\u0646<\/h4><p style='text-align: left; font-weight:bold;'>Nasreldin M. Mahmoud<sup>1<\/sup><\/p><div style='direction: ltr; text-align: left; font-size:12px; line-height:1.5;'><p>\"1 Mechanical Engineering Department, Faculty of Engineering, University of Sinnar, Sinnar, Sudan<\/p><p>*Corresponding author. Mechanical Engineering Department, Faculty of Engineering, University of Sinnar, Sinnar, Sudan<\/p><p>E-mail address: nasrmohamed53@hotmail.com ; nasrmohamed@uofs.edu.sd.\"<\/p><\/div><p style='text-align:left;'><strong>DOI:<\/strong> <a href='https:\/\/doi.org\/https:\/\/doi.org\/10.53796\/hnsj71\/32' target='_blank' rel='noopener'>https:\/\/doi.org\/10.53796\/hnsj71\/32<\/a><\/p><p style='text-align: left;'><strong>Arabic Scientific Research Identifier:<\/strong> <a href='https:\/\/arsri.org\/10000\/71\/32' target='_blank' rel='noopener'>https:\/\/arsri.org\/10000\/71\/32<\/a><\/p><p style='text-align: left;'><strong>Volume (7) Issue (1). Pages:<\/strong> 503 - 510<\/p><p style='text-align: left;'><strong>Received at:<\/strong> 2025-12-10 | <strong>Accepted at:<\/strong> 2025-12-17 | <strong>Published at:<\/strong> 2026-01-01<\/p><p><a href='\/volume7\/issue1\/7-1-32.pdf' target='_blank' rel='noopener' style='background-color:green;color:white;padding:10px 15px;text-decoration:none;border-radius:5px;'>Download PDF<\/a><\/p>\r\n<style>\r\n.hnsj-cite-btn{\r\n  display:inline-flex; gap:8px; align-items:center;\r\n  padding:10px 14px; border-radius:10px;\r\n  border:1px solid #0b5ed7; background:#0b5ed7; color:#fff;\r\n  cursor:pointer; font-weight:700;\r\n}\r\n.hnsj-cite-btn:hover{background:#084bb0;border-color:#084bb0}\r\n.hnsj-cite-note{display:block;margin-top:6px;font-size:13px;opacity:.85}\r\n\r\n.hnsj-modal-backdrop{\r\n  position:fixed; inset:0; background:rgba(0,0,0,.55);\r\n  display:none; z-index:99998;\r\n}\r\n.hnsj-modal{\r\n  position:fixed; left:50%; top:50%; transform:translate(-50%,-50%);\r\n  width:min(760px,94vw); background:#fff; border-radius:14px;\r\n  box-shadow:0 12px 35px rgba(0,0,0,.28);\r\n  display:none; z-index:99999; overflow:hidden;\r\n  border:1px solid rgba(0,0,0,.08);\r\n}\r\n\r\n.hnsj-modal-header{\r\n  display:flex; justify-content:space-between; align-items:center;\r\n  padding:14px 16px; border-bottom:1px solid #eee; background:#f8fafc;\r\n}\r\n.hnsj-modal-title{font-size:16px;font-weight:800;color:#111827}\r\n.hnsj-modal-close{\r\n  border:1px solid #d1d5db; background:#fff;\r\n  width:34px; height:34px; border-radius:10px;\r\n  font-size:18px; cursor:pointer; line-height:0; color:#111827;\r\n}\r\n.hnsj-modal-close:hover{background:#f3f4f6}\r\n\r\n.hnsj-tabs{\r\n  display:flex; gap:10px; padding:10px 16px;\r\n  border-bottom:1px solid #f0f0f0; justify-content:flex-end;\r\n}\r\n.hnsj-tab{\r\n  padding:10px 14px; border-radius:10px;\r\n  border:1px solid #cfcfcf; background:#f3f4f6;\r\n  cursor:pointer; font-weight:800; color:#111827;\r\n}\r\n.hnsj-tab:hover{background:#e5e7eb;border-color:#9ca3af}\r\n.hnsj-tab.active{\r\n  background:#0b5ed7; border-color:#0b5ed7; color:#fff;\r\n  box-shadow:0 2px 10px rgba(11,94,215,.18);\r\n}\r\n\r\n.hnsj-modal-body{padding:14px 16px}\r\n.hnsj-row{\r\n  display:flex; gap:10px; flex-wrap:wrap; align-items:center;\r\n  margin-bottom:10px; justify-content:flex-end;\r\n}\r\n.hnsj-select{\r\n  padding:10px 12px; border-radius:10px;\r\n  border:1px solid #cfcfcf; min-width:220px;\r\n  background:#fff; color:#111827; font-weight:700;\r\n}\r\n.hnsj-copy{\r\n  padding:10px 14px; border-radius:10px;\r\n  border:1px solid #0b5ed7; background:#0b5ed7; color:#fff;\r\n  cursor:pointer; font-weight:800;\r\n}\r\n.hnsj-copy:hover{background:#084bb0;border-color:#084bb0}\r\n\r\n.hnsj-textarea{\r\n  width:100%; min-height:130px; padding:12px;\r\n  border-radius:12px; border:1px solid #cfcfcf;\r\n  line-height:1.7; resize:vertical; color:#111827; background:#fff;\r\n}\r\n.hnsj-actions{display:flex; justify-content:space-between; align-items:center; margin-top:10px; gap:10px; flex-wrap:wrap;}\r\n.hnsj-dl{\r\n  padding:10px 14px;\r\n  border-radius:10px;\r\n  border:1px solid #0b5ed7;\r\n  background:#0b5ed7;\r\n  color:#fff;\r\n  cursor:pointer;\r\n  font-weight:800;\r\n}\r\n.hnsj-dl:hover{background:#084bb0;border-color:#084bb0}\r\n\/* Force the citation modal UI to be independent from site RTL\/LTR *\/\r\n.hnsj-modal,\r\n.hnsj-modal *{\r\n  direction: ltr;\r\n  text-align: left;\r\n}\r\n\r\n\/* Keep the header title readable *\/\r\n.hnsj-modal-header{\r\n  direction: ltr;\r\n}\r\n<\/style>\r\n\r\n<script>\r\n(function(){\r\n  function slugifyFileName(s){\r\n    return (s || 'citation')\r\n      .toString()\r\n      .trim()\r\n      .replace(\/^https?:\\\/\\\/\/i,'')\r\n      .replace(\/[^a-z0-9]+\/gi,'-')\r\n      .replace(\/-+\/g,'-')\r\n      .replace(\/^-|-$\/g,'')\r\n      .toLowerCase();\r\n  }\r\n\r\n  function downloadTextFile(filename, content, mime){\r\n    var blob = new Blob([content], { type: mime || 'text\/plain;charset=utf-8' });\r\n    var url = URL.createObjectURL(blob);\r\n    var a = document.createElement('a');\r\n    a.href = url;\r\n    a.download = filename;\r\n    document.body.appendChild(a);\r\n    a.click();\r\n    a.remove();\r\n    setTimeout(function(){ URL.revokeObjectURL(url); }, 500);\r\n  }\r\n\r\n  function splitAuthors(str){\r\n    if(!str) return [];\r\n    return str\r\n      .split(\/,|\u061b|\u060c|;|\\n\/g)\r\n      .map(s => s.trim())\r\n      .filter(Boolean);\r\n  }\r\n\r\n  function buildRIS(m, langKey){\r\n    const title   = (langKey === 'ar') ? 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M.. (2026). Studying the Mechanism of Soot Reduction via Co-Combustion of Methane in a Laminar n-heptane Diffusion Flame. Humanities &amp; Natural Sciences Journal, 7(1). https:\\\/\\\/doi.org\\\/10.53796\\\/hnsj71\\\/32&quot;,&quot;Chicago&quot;:&quot;Nasreldin M. Mahmoud. 2026. \\&quot;Studying the Mechanism of Soot Reduction via Co-Combustion of Methane in a Laminar n-heptane Diffusion Flame.\\&quot; Humanities &amp; Natural Sciences Journal 7, no. 1. https:\\\/\\\/doi.org\\\/10.53796\\\/hnsj71\\\/32&quot;,&quot;Harvard&quot;:&quot;Mahmoud N. M.. 2026. Studying the Mechanism of Soot Reduction via Co-Combustion of Methane in a Laminar n-heptane Diffusion Flame. Humanities &amp; Natural Sciences Journal. [Internet] 2026-01-01. [Cited 2026-04-24]. 7(1). Available at: https:\\\/\\\/www.hnjournal.net\\\/7-1-32\\\/. https:\\\/\\\/doi.org\\\/10.53796\\\/hnsj71\\\/32&quot;,&quot;Vancouver&quot;:&quot;Mahmoud N. M.. Studying the Mechanism of Soot Reduction via Co-Combustion of Methane in a Laminar n-heptane Diffusion Flame. Humanities &amp; Natural Sciences Journal. [Internet]. 2026-01-01; 7(1). Available from: https:\\\/\\\/doi.org\\\/10.53796\\\/hnsj71\\\/32&quot;,&quot;IEEE&quot;:&quot;Mahmoud N. M., \\&quot;Studying the Mechanism of Soot Reduction via Co-Combustion of Methane in a Laminar n-heptane Diffusion Flame,\\&quot; Humanities &amp; Natural Sciences Journal, vol. 7, no. 1, 2026. https:\\\/\\\/doi.org\\\/10.53796\\\/hnsj71\\\/32&quot;,&quot;MLA&quot;:&quot;Nasreldin M. Mahmoud. \\&quot;Studying the Mechanism of Soot Reduction via Co-Combustion of Methane in a Laminar n-heptane Diffusion Flame.\\&quot; Humanities &amp; Natural Sciences Journal, vol. 7, no. 1, 2026-01-01, https:\\\/\\\/doi.org\\\/10.53796\\\/hnsj71\\\/32&quot;}' data-cit-ar='{&quot;APA&quot;:&quot;Mahmoud N. M. (2026). \u062f\u0631\u0627\u0633\u0629 \u0622\u0644\u064a\u0629 \u062a\u0642\u0644\u064a\u0644 \u062a\u0643\u0648\u0651\u0646 \u0627\u0644\u0633\u0646\u0627\u062c \u0645\u0646 \u062e\u0644\u0627\u0644 \u0627\u0644\u0627\u062d\u062a\u0631\u0627\u0642 \u0627\u0644\u0645\u0634\u062a\u0631\u0643 \u0644\u0644\u0645\u064a\u062b\u0627\u0646 \u0641\u064a \u0644\u0647\u0628 \u0627\u0646\u062a\u0634\u0627\u0631 \u0635\u0641\u062d\u064a \u0644\u063a\u0627\u0632 n-\u0647\u064a\u0628\u062a\u0627\u0646. \u0645\u062c\u0644\u0629 \u0627\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0627\u0646\u0633\u0627\u0646\u064a\u0629 \u0648\u0627\u0644\u0637\u0628\u064a\u0639\u064a\u0629\u060c 7(1). https:\\\/\\\/doi.org\\\/10.53796\\\/hnsj71\\\/32&quot;,&quot;Chicago&quot;:&quot;Mahmoud Nasreldin M.. 2026. \u00ab\u062f\u0631\u0627\u0633\u0629 \u0622\u0644\u064a\u0629 \u062a\u0642\u0644\u064a\u0644 \u062a\u0643\u0648\u0651\u0646 \u0627\u0644\u0633\u0646\u0627\u062c \u0645\u0646 \u062e\u0644\u0627\u0644 \u0627\u0644\u0627\u062d\u062a\u0631\u0627\u0642 \u0627\u0644\u0645\u0634\u062a\u0631\u0643 \u0644\u0644\u0645\u064a\u062b\u0627\u0646 \u0641\u064a \u0644\u0647\u0628 \u0627\u0646\u062a\u0634\u0627\u0631 \u0635\u0641\u062d\u064a \u0644\u063a\u0627\u0632 n-\u0647\u064a\u0628\u062a\u0627\u0646\u00bb. \u0645\u062c\u0644\u0629 \u0627\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0627\u0646\u0633\u0627\u0646\u064a\u0629 \u0648\u0627\u0644\u0637\u0628\u064a\u0639\u064a\u0629\u060c 7(1). https:\\\/\\\/doi.org\\\/10.53796\\\/hnsj71\\\/32&quot;,&quot;Harvard&quot;:&quot;Mahmoud N. M. \u062f\u0631\u0627\u0633\u0629 \u0622\u0644\u064a\u0629 \u062a\u0642\u0644\u064a\u0644 \u062a\u0643\u0648\u0651\u0646 \u0627\u0644\u0633\u0646\u0627\u062c \u0645\u0646 \u062e\u0644\u0627\u0644 \u0627\u0644\u0627\u062d\u062a\u0631\u0627\u0642 \u0627\u0644\u0645\u0634\u062a\u0631\u0643 \u0644\u0644\u0645\u064a\u062b\u0627\u0646 \u0641\u064a \u0644\u0647\u0628 \u0627\u0646\u062a\u0634\u0627\u0631 \u0635\u0641\u062d\u064a \u0644\u063a\u0627\u0632 n-\u0647\u064a\u0628\u062a\u0627\u0646. \u0645\u062c\u0644\u0629 \u0627\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0627\u0646\u0633\u0627\u0646\u064a\u0629 \u0648\u0627\u0644\u0637\u0628\u064a\u0639\u064a\u0629. [\u0627\u0646\u062a\u0631\u0646\u062a] 2026-01-01. [\u062a\u0627\u0631\u064a\u062e \u0627\u0644\u0648\u0635\u0648\u0644 2026-04-24]. 7(1). \u0645\u062a\u0627\u062d \u0639\u0644\u0649: https:\\\/\\\/www.hnjournal.net\\\/7-1-32\\\/. https:\\\/\\\/doi.org\\\/10.53796\\\/hnsj71\\\/32&quot;,&quot;Vancouver&quot;:&quot;Mahmoud N. M. \u062f\u0631\u0627\u0633\u0629 \u0622\u0644\u064a\u0629 \u062a\u0642\u0644\u064a\u0644 \u062a\u0643\u0648\u0651\u0646 \u0627\u0644\u0633\u0646\u0627\u062c \u0645\u0646 \u062e\u0644\u0627\u0644 \u0627\u0644\u0627\u062d\u062a\u0631\u0627\u0642 \u0627\u0644\u0645\u0634\u062a\u0631\u0643 \u0644\u0644\u0645\u064a\u062b\u0627\u0646 \u0641\u064a \u0644\u0647\u0628 \u0627\u0646\u062a\u0634\u0627\u0631 \u0635\u0641\u062d\u064a \u0644\u063a\u0627\u0632 n-\u0647\u064a\u0628\u062a\u0627\u0646. \u0645\u062c\u0644\u0629 \u0627\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0627\u0646\u0633\u0627\u0646\u064a\u0629 \u0648\u0627\u0644\u0637\u0628\u064a\u0639\u064a\u0629. [\u0627\u0646\u062a\u0631\u0646\u062a]. 2026-01-01\u061b 7(1). \u0645\u062a\u0627\u062d \u0645\u0646: https:\\\/\\\/doi.org\\\/10.53796\\\/hnsj71\\\/32&quot;,&quot;IEEE&quot;:&quot;Mahmoud N. M. \u00ab\u062f\u0631\u0627\u0633\u0629 \u0622\u0644\u064a\u0629 \u062a\u0642\u0644\u064a\u0644 \u062a\u0643\u0648\u0651\u0646 \u0627\u0644\u0633\u0646\u0627\u062c \u0645\u0646 \u062e\u0644\u0627\u0644 \u0627\u0644\u0627\u062d\u062a\u0631\u0627\u0642 \u0627\u0644\u0645\u0634\u062a\u0631\u0643 \u0644\u0644\u0645\u064a\u062b\u0627\u0646 \u0641\u064a \u0644\u0647\u0628 \u0627\u0646\u062a\u0634\u0627\u0631 \u0635\u0641\u062d\u064a \u0644\u063a\u0627\u0632 n-\u0647\u064a\u0628\u062a\u0627\u0646\u00bb. \u0645\u062c\u0644\u0629 \u0627\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0627\u0646\u0633\u0627\u0646\u064a\u0629 \u0648\u0627\u0644\u0637\u0628\u064a\u0639\u064a\u0629\u060c \u0645 7\u060c \u0639 1\u060c 2026. https:\\\/\\\/doi.org\\\/10.53796\\\/hnsj71\\\/32&quot;,&quot;MLA&quot;:&quot;Mahmoud Nasreldin M.. \u00ab\u062f\u0631\u0627\u0633\u0629 \u0622\u0644\u064a\u0629 \u062a\u0642\u0644\u064a\u0644 \u062a\u0643\u0648\u0651\u0646 \u0627\u0644\u0633\u0646\u0627\u062c \u0645\u0646 \u062e\u0644\u0627\u0644 \u0627\u0644\u0627\u062d\u062a\u0631\u0627\u0642 \u0627\u0644\u0645\u0634\u062a\u0631\u0643 \u0644\u0644\u0645\u064a\u062b\u0627\u0646 \u0641\u064a \u0644\u0647\u0628 \u0627\u0646\u062a\u0634\u0627\u0631 \u0635\u0641\u062d\u064a \u0644\u063a\u0627\u0632 n-\u0647\u064a\u0628\u062a\u0627\u0646\u00bb. \u0645\u062c\u0644\u0629 \u0627\u0644\u0639\u0644\u0648\u0645 \u0627\u0644\u0627\u0646\u0633\u0627\u0646\u064a\u0629 \u0648\u0627\u0644\u0637\u0628\u064a\u0639\u064a\u0629\u060c \u0645 7\u060c \u0639 1\u060c 2026-01-01\u060c https:\\\/\\\/doi.org\\\/10.53796\\\/hnsj71\\\/32&quot;}'>\r\n    <div class='hnsj-modal-header'>\r\n    <div class='hnsj-modal-title'>Cite \/ \u0627\u0644\u0627\u0633\u062a\u0634\u0647\u0627\u062f<\/div>\r\n    <button class='hnsj-modal-close' type='button' data-hnsj-close aria-label='Close'>\u00d7<\/button>\r\n    <\/div>\r\n\r\n    <div class='hnsj-tabs'>\r\n      <button type='button' class='hnsj-tab active' data-lang='en'>English (Roman)<\/button>\r\n      <button type='button' class='hnsj-tab' data-lang='ar'>\u0627\u0644\u0639\u0631\u0628\u064a\u0629<\/button>\r\n    <\/div>\r\n\r\n    <div class='hnsj-modal-body'>\r\n      <div class='hnsj-row'>\r\n        <button type='button' class='hnsj-copy' data-hnsj-copy>Copy<\/button>\r\n        <select class='hnsj-select' data-hnsj-style><\/select>\r\n        <\/div>\r\n\r\n      <textarea class='hnsj-textarea' data-hnsj-box readonly><\/textarea>\r\n\r\n      <div class='hnsj-actions'>\r\n        <div style='display:flex; gap:10px; flex-wrap:wrap;'>\r\n          <button type='button' class='hnsj-dl' data-hnsj-dl='ris'>Download RIS<\/button>\r\n          <button type='button' class='hnsj-dl' data-hnsj-dl='bib'>Download BibTeX<\/button>\r\n        <\/div>\r\n      <\/div>\r\n    <\/div>\r\n  <\/div>\r\n<\/div>\r\n<p style='text-align:justify; direction:ltr;'><strong>Abstract:<\/strong> The combustion of n-heptane\/methane mixtures in dual-fuel systems presents a promising strategy for reducing soot emissions, yet the underlying suppression mechanisms require further quantification. This study employs numerical simulation to investigate the structural and effects of methane addition on a laminar n-heptane diffusion flame. A validated coupled model, incorporating detailed chemical kinetics mechanism and a discrete sectional soot model, is applied. Simulations results reveal that methane blending significantly suppresses soot volume fraction, with the normalized peak value decreasing monotonically with methane addition. While the peak flame temperature remains stable, the entire thermal structure shifts toward the fuel nozzle due to altered mixture reactivity. Analysis of key intermediates shows that methane addition reduces peak concentrations of aromatic precursors, with a progressively stronger inhibition effect observed for larger polycyclic aromatic hydrocarbons. This size-dependent suppression indicates that methane chemically interferes with molecular growth processes beyond the first aromatic ring, likely through perturbation of the H-abstraction-C\u2082H\u2082-addition (HACA) mechanism and radical pool modification. The results elucidate the combined dilution and chemical effects governing soot reduction, providing critical insights for optimizing dual-fuel combustion towards minimal particulate emissions.<\/p><p style='text-align:left; direction:ltr;'><strong>Keywords: <\/strong> Dual-fuel combustion; Soot formation; Polycyclic aromatic hydrocarbons (PAH); Diffusion flame.<\/p><p style='text-align:justify; direction:rtl;'><strong>\u0627\u0644\u0645\u0633\u062a\u062e\u0644\u0635: <\/strong> \u064a\u064f\u0639\u062f \u0627\u062d\u062a\u0631\u0627\u0642 \u062e\u0644\u0637\u0627\u062a n-\u0647\u064a\u0628\u062a\u0627\u0646\/\u0627\u0644\u0645\u064a\u062b\u0627\u0646 \u0641\u064a \u0623\u0646\u0638\u0645\u0629 \u0627\u0644\u0648\u0642\u0648\u062f \u0627\u0644\u0645\u0632\u062f\u0648\u062c \u0627\u0633\u062a\u0631\u0627\u062a\u064a\u062c\u064a\u0629 \u0648\u0627\u0639\u062f\u0629 \u0644\u0644\u062d\u062f \u0645\u0646 \u0627\u0646\u0628\u0639\u0627\u062b\u0627\u062a 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\u0643\u0645\u0627 \u064a\u0643\u0634\u0641 \u062a\u062d\u0644\u064a\u0644 \u0627\u0644\u0645\u062a\u0648\u0633\u0651\u0650\u0637\u0627\u062a \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0626\u064a\u0629 \u0627\u0644\u0631\u0626\u064a\u0633\u0629 \u0623\u0646 \u0625\u0636\u0627\u0641\u0629 \u0627\u0644\u0645\u064a\u062b\u0627\u0646 \u062a\u0642\u0644\u0644 \u0645\u0646 \u0627\u0644\u0642\u064a\u0645 \u0627\u0644\u0639\u0638\u0645\u0649 \u0644\u062a\u0631\u0643\u064a\u0632\u0627\u062a \u0627\u0644\u0633\u0648\u0627\u0628\u0642 \u0627\u0644\u0639\u0637\u0631\u064a\u0629\u060c \u0645\u0639 \u0645\u0644\u0627\u062d\u0638\u0629 \u062a\u0623\u062b\u064a\u0631 \u062a\u062b\u0628\u064a\u0637\u064a \u0645\u062a\u0632\u0627\u064a\u062f \u0643\u0644\u0645\u0627 \u0627\u0632\u062f\u0627\u062f \u062d\u062c\u0645 \u0627\u0644\u0647\u064a\u062f\u0631\u0648\u0643\u0631\u0628\u0648\u0646\u0627\u062a \u0627\u0644\u0639\u0637\u0631\u064a\u0629 \u0645\u062a\u0639\u062f\u062f\u0629 \u0627\u0644\u062d\u0644\u0642\u0627\u062a.\r\n\u064a\u0634\u064a\u0631 \u0647\u0630\u0627 \u0627\u0644\u062a\u062b\u0628\u064a\u0637 \u0627\u0644\u0645\u0639\u062a\u0645\u062f \u0639\u0644\u0649 \u0627\u0644\u062d\u062c\u0645 \u0625\u0644\u0649 \u0623\u0646 \u0627\u0644\u0645\u064a\u062b\u0627\u0646 \u064a\u062a\u062f\u0627\u062e\u0644 \u0643\u064a\u0645\u064a\u0627\u0626\u064a\u0627\u064b \u0645\u0639 \u0639\u0645\u0644\u064a\u0627\u062a \u0627\u0644\u0646\u0645\u0648 \u0627\u0644\u062c\u0632\u064a\u0626\u064a \u0644\u0645\u0627 \u0628\u0639\u062f \u062a\u0643\u0648\u0651\u0646 \u0627\u0644\u062d\u0644\u0642\u0629 \u0627\u0644\u0639\u0637\u0631\u064a\u0629 \u0627\u0644\u0623\u0648\u0644\u0649\u060c \u0648\u064a\u0631\u062c\u0651\u064e\u062d \u0623\u0646 \u064a\u0643\u0648\u0646 \u0630\u0644\u0643 \u0645\u0646 \u062e\u0644\u0627\u0644 \u0625\u0631\u0628\u0627\u0643 \u0622\u0644\u064a\u0629 \u0646\u0632\u0639 \u0627\u0644\u0647\u064a\u062f\u0631\u0648\u062c\u064a\u0646\u2013\u0625\u0636\u0627\u0641\u0629 \u0627\u0644\u0623\u0633\u064a\u062a\u064a\u0644\u064a\u0646 (HACA) \u0648\u062a\u0639\u062f\u064a\u0644 \u062a\u062c\u0645\u0639 \u0627\u0644\u062c\u0630\u0648\u0631 \u0627\u0644\u062d\u0631\u0629. \u0648\u062a\u0648\u0636\u062d \u0647\u0630\u0647 \u0627\u0644\u0646\u062a\u0627\u0626\u062c \u0627\u0644\u062a\u0623\u062b\u064a\u0631\u0627\u062a \u0627\u0644\u0645\u0634\u062a\u0631\u0643\u0629 \u0644\u0644\u062a\u062e\u0641\u064a\u0641 \u0648\u0627\u0644\u062a\u062f\u0627\u062e\u0644 \u0627\u0644\u0643\u064a\u0645\u064a\u0627\u0626\u064a \u0627\u0644\u062a\u064a \u062a\u062a\u062d\u0643\u0645 \u0641\u064a \u062e\u0641\u0636 \u062a\u0643\u0648\u0651\u0646 \u0627\u0644\u0633\u0646\u0627\u062c\u060c \u0645\u0645\u0627 \u064a\u0648\u0641\u0631 \u0631\u0624\u0649 \u0623\u0633\u0627\u0633\u064a\u0629 \u0644\u062a\u062d\u0633\u064a\u0646 \u0627\u062d\u062a\u0631\u0627\u0642 \u0627\u0644\u0648\u0642\u0648\u062f \u0627\u0644\u0645\u0632\u062f\u0648\u062c \u0628\u0647\u062f\u0641 \u062a\u0642\u0644\u064a\u0644 \u0627\u0644\u0627\u0646\u0628\u0639\u0627\u062b\u0627\u062a \u0627\u0644\u062c\u0633\u064a\u0645\u064a\u0629 \u0625\u0644\u0649 \u0623\u062f\u0646\u0649 \u062d\u062f.\r\n<\/p><p style='text-align:right;'><strong>\u0627\u0644\u0643\u0644\u0645\u0627\u062a \u0627\u0644\u0645\u0641\u062a\u0627\u062d\u064a\u0629: <\/strong> \u0627\u0644\u0627\u062d\u062a\u0631\u0627\u0642 \u062b\u0646\u0627\u0626\u064a \u0627\u0644\u0648\u0642\u0648\u062f\u061b \u062a\u0643\u0648\u0651\u0646 \u0627\u0644\u0633\u0646\u0627\u062c\u061b \u0627\u0644\u0647\u064a\u062f\u0631\u0648\u0643\u0631\u0628\u0648\u0646\u0627\u062a \u0627\u0644\u0639\u0637\u0631\u064a\u0629 \u0645\u062a\u0639\u062f\u062f\u0629 \u0627\u0644\u062d\u0644\u0642\u0627\u062a (PAH)\u061b \u0644\u0647\u0628 \u0627\u0644\u0627\u0646\u062a\u0634\u0627\u0631.<\/p><\/div>\n\n\n<h1 dir=\"ltr\" style=\"text-align: justify;\">Introduction<\/h1>\n<p dir=\"ltr\" style=\"text-align: justify;\">Increasing global challenges, including oil shortages and air pollution, have highlighted the urgent need for advanced, sustainable power transmission solutions in the transportation industry [1]. In this context, natural gas (mainly methane) has emerged as a promising alternative fuel due to its abundant reserves, lower carbon-to\u2011hydrogen ratio compared to conventional liquid hydrocarbons, and potential to reduce greenhouse gas and pollutant emissions [2]. Co\u2011firing natural gas with traditional liquid fuels in dual\u2011fuel combustion strategies offers a practical pathway for decarbonizing internal combustion engines and gas turbines. However, the fundamental chemical interactions between methane and higher hydrocarbons during combustion, particularly their combined impact on soot formation pathways, remain insufficiently quantified. Soot emissions are a critical concern for air quality and human health, and their formation is intricately linked to the complex pyrolysis chemistry of fuels, including the growth of polycyclic aromatic hydrocarbons (PAHs) [3]. This study investigates the structural and chemical effects of methane addition on a laminar diffusion flame of n\u2011heptane (a common diesel surrogate) using detailed numerical simulation. The work specifically examines the evolution of flame temperature, key intermediate species, PAHs, and soot volume fraction to elucidate the chemical and physical mechanisms by which methane moderates soot production. Validations are performed against established experimental data to ensure model fidelity, providing insights critical for optimizing dual\u2011fuel systems towards minimal particulate emissions.<\/p>\n<h1 dir=\"ltr\" style=\"text-align: justify;\">Numerical Methodology<\/h1>\n<p dir=\"ltr\" style=\"text-align: justify;\"><em>2.1 Burner Configurations <\/em><\/p>\n<p dir=\"ltr\" style=\"text-align: justify;\">The counterflow diffusion flame configuration was selected for this study due to its well-defined, quasi-one-dimensional structure, which is highly amenable to detailed numerical simulation and provides a canonical framework for investigating soot kinetics. The configuration consists of two vertically opposed nozzles, with the fuel mixture n-heptane and methane issuing from the lower nozzle and the oxidizer (air) from the upper nozzle, separated by a distance of <em>L<\/em>. The simulations were performed using an opposed-flow module that solves the governing equations for mass, momentum, energy, and species conservation in an axisymmetric geometry [4]. By assuming a plug-flow velocity profile at the boundaries and a linear radial velocity variation, the system of partial differential equations can be reduced to a set of ordinary differential equations dependent solely on the axial coordinate. This one-dimensional approximation significantly enhances computational efficiency while retaining the essential physics for studying detailed chemistry and soot formation. Radiation heat loss from major gaseous species (CO, CO\u2082, H\u2082O, CH\u2084) and soot particles was accounted for using the optically thin approximation, neglecting self-absorption [5, 6]. A constant global strain rate of\u00a0<em>K<\/em>\u00a0= 50 s\u207b\u00b9 was maintained for all simulated flames to ensure consistent aerodynamic conditions, with the nozzle exit velocities adjusted accordingly for different fuel compositions [7].<\/p>\n<h2 dir=\"ltr\" style=\"text-align: justify;\">2.2. Chemical Kinetic Mechanism and Soot Model<\/h2>\n<p dir=\"ltr\" style=\"text-align: justify;\">The gas-phase kinetics were described by a detailed chemical mechanism developed for the combustion of practical fuel components, including a validated sub-mechanism for n-heptane oxidation [8]. This mechanism, comprising 291 species and 1223 elementary reactions, includes comprehensive PAH formation chemistry up to pyrene (A4). A well-established methane oxidation sub-mechanism was integrated to accurately capture its pyrolysis and oxidation pathways. Soot formation was modeled using a discrete sectional method (DSM) [9-11]. The particle size distribution was discretized into 30 sections, with the volume of each successive section doubling that of the previous one. Soot inception was modeled via the dimerization of pyrene (A\u2084) molecules. Subsequent particle evolution was governed by key processes: surface growth via the hydrogen-abstraction-acetylene-addition (HACA) mechanism [12, 13], physical condensation of gas-phase PAHs, particle coagulation in the free-molecular regime (enhanced by a Van der Waals factor of 2.2 [14]), and oxidation by O\u2082 and OH radicals. Oxidation rates by O\u2082 were adopted from established models [15], while a constant collision efficiency of \u03b3_OH = 0.13 was used for OH oxidation [16].<\/p>\n<h2 dir=\"ltr\" style=\"text-align: justify;\">2.3. Boundary Conditions and Case Definition<\/h2>\n<p dir=\"ltr\" style=\"text-align: justify;\">The baseline condition simulates a diluted n-heptane\/air flame, replicating the previous experimental setup [17, 18]. The fuel stream composition (mole fraction) was 0.4 C\u2087H\u2081\u2086 and 0.6 N\u2082, while the oxidizer stream was composed of 0.21 O\u2082 and 0.79 N\u2082 (air). Both fuel and oxidizer inlet temperatures were fixed at 400 K. To investigate the effect of methane addition, n-heptane in the fuel stream was partially replaced by CH\u2084. The methane doping ratio, R<sub>CH4<\/sub>, is defined as:<\/p>\n<p dir=\"ltr\" style=\"text-align: justify;\">where x denotes mole fraction. The total mole fraction of the carbon-containing fuel (C\u2087H\u2081\u2086 + CH\u2084) was kept constant at 0.4, with nitrogen making up the remaining 0.6 of the fuel streams. Cases with R<sub>CH\u2084<\/sub> = 0 (pure n-heptane), 0.2, and 0.4 were simulated to gradually assess the impact of methane blending.<\/p>\n<h1 dir=\"ltr\" style=\"text-align: justify;\">Model Validations and Flame Structure<\/h1>\n<p dir=\"ltr\" style=\"text-align: justify;\">Prior to analyzing the effects of methane addition, the predictive capability of the coupled gas-phase and soot models was rigorously validated against experimental data for the baseline n-heptane flame. Figure 3\u00a0presents the predicted flame structure for the baseline n\u2011heptane (C\u2087H\u2081\u2086) flame, validated against experimental data [17, 18]. Panel (a) shows excellent agreement between predicted and measured temperature profiles along the central axis, confirming the model&#8217;s accuracy in capturing thermal characteristics. As expected, n\u2011heptane fuel concentration decreases monotonically from the nozzle, depleting entirely at the flame sheet (coincident with the peak temperature, (X<sub>T,max<\/sub>), while oxygen concentration diminishes from the oxidizer side. Critical pyrolysis intermediates such as C\u2082H\u2082 and C\u2083H\u2083 are present exclusively on the fuel\u2011rich side, serving as vital precursors for PAH formation [6]. Panel (b) illustrates the spatial distribution of aromatic species (A1: benzene, A2: naphthalene, A3: phenanthrene, A4: pyrene) and the computed soot volume fraction (SVF). The peak concentrations of PAHs are located within the high\u2011temperature region, consistent with established understanding that PAH growth is thermally promoted [19-22]. The predicted SVF profile and its peak magnitude align well with the experimental measurements [17, 18], although a slight spatial discrepancy in the peak location is observed, potentially attributable to uncertainties in the soot model&#8217;s treatment of particle transport or oxidation.<\/p>\n<p dir=\"ltr\" style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" width=\"766\" height=\"1096\" class=\"wp-image-15534\" src=\"http:\/\/www.hnjournal.net\/wp-content\/uploads\/2025\/12\/word-image-15525-1.png\" srcset=\"https:\/\/www.hnjournal.net\/wp-content\/uploads\/2025\/12\/word-image-15525-1.png 766w, https:\/\/www.hnjournal.net\/wp-content\/uploads\/2025\/12\/word-image-15525-1-210x300.png 210w, https:\/\/www.hnjournal.net\/wp-content\/uploads\/2025\/12\/word-image-15525-1-716x1024.png 716w, https:\/\/www.hnjournal.net\/wp-content\/uploads\/2025\/12\/word-image-15525-1-8x12.png 8w\" sizes=\"auto, (max-width: 766px) 100vw, 766px\" \/><\/p>\n<p dir=\"ltr\" style=\"text-align: justify;\">Figure 3. Predicted flame structures of baseline C<sub>7<\/sub>H<sub>16<\/sub> flame; (a) flame temperature and relevant important species profiles; (b) the computed soot volume fraction profiles along with A1, A2, A3, and A4. The experimental results of temperature and soot volume fraction adopted from [17, 18] are also plotted for validations (symbols).<\/p>\n<p dir=\"ltr\" style=\"text-align: justify;\">Figure 5\u00a0compares the soot volume fraction for pure n\u2011heptane and n\u2011heptane\/methane mixture flames. Panel (a) demonstrates that methane addition consistently reduces the spatial SVF profile. Panel (b) quantifies this effect through the normalized maximum SVF, revealing a suppression of soot formation with increasing methane doping ratio. This suppression can be attributed to a combination of\u00a0dilution\u00a0and\u00a0chemical\u00a0effects. Methane, being a single\u2011carbon molecule, dilutes the pool of available soot precursors from n\u2011heptane pyrolysis. Furthermore, its stable C\u2011H bonds and distinct pyrolysis pathways can chemically inhibit the growth of larger aromatic clusters by altering the H\u2011abstraction\u2011C\u2082H\u2082\u2011addition (HACA) reaction pathway or competing for key radicals [20, 21, 23, 24]. The observed trend is consistent with previous studies on hydrocarbon blending effects on soot yields [25] .<\/p>\n<p dir=\"ltr\" style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" width=\"1280\" height=\"1831\" class=\"wp-image-15535\" src=\"http:\/\/www.hnjournal.net\/wp-content\/uploads\/2025\/12\/word-image-15525-2.png\" srcset=\"https:\/\/www.hnjournal.net\/wp-content\/uploads\/2025\/12\/word-image-15525-2.png 1280w, https:\/\/www.hnjournal.net\/wp-content\/uploads\/2025\/12\/word-image-15525-2-210x300.png 210w, https:\/\/www.hnjournal.net\/wp-content\/uploads\/2025\/12\/word-image-15525-2-716x1024.png 716w, https:\/\/www.hnjournal.net\/wp-content\/uploads\/2025\/12\/word-image-15525-2-768x1099.png 768w, https:\/\/www.hnjournal.net\/wp-content\/uploads\/2025\/12\/word-image-15525-2-1074x1536.png 1074w, https:\/\/www.hnjournal.net\/wp-content\/uploads\/2025\/12\/word-image-15525-2-8x12.png 8w\" sizes=\"auto, (max-width: 1280px) 100vw, 1280px\" \/><\/p>\n<p dir=\"ltr\" style=\"text-align: justify;\">Figure 4. Comparison of soot volume fraction profile (a) and normalized max of (<em>f<sub>v<\/sub><\/em>) (b) of n-heptane with increasing methane blending ratio.<\/p>\n<p dir=\"ltr\" style=\"text-align: justify;\">The influence of methane addition on flame temperature is a critical factor, as temperature governs pyrolysis, oxidation, and soot formation kinetics [26]. The results indicate that the peak flame temperature remains largely unchanged with methane blending. However, the entire temperature profile shifts spatially towards the fuel nozzle. This shift is likely a consequence of the altered\u00a0fuel stream momentum\u00a0and\u00a0reactivity\u00a0of the mixture; methane&#8217;s different ignition delay and lower adiabatic flame temperature can modify the local stoichiometry and heat release distribution [24, 27]. This thermal field shift has direct implications for precursor chemistry, as evidenced in the subsequent analysis of PAHs.<\/p>\n<p dir=\"ltr\" style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" width=\"641\" height=\"519\" class=\"wp-image-15536\" src=\"http:\/\/www.hnjournal.net\/wp-content\/uploads\/2025\/12\/word-image-15525-3.png\" srcset=\"https:\/\/www.hnjournal.net\/wp-content\/uploads\/2025\/12\/word-image-15525-3.png 641w, https:\/\/www.hnjournal.net\/wp-content\/uploads\/2025\/12\/word-image-15525-3-300x243.png 300w, https:\/\/www.hnjournal.net\/wp-content\/uploads\/2025\/12\/word-image-15525-3-15x12.png 15w\" sizes=\"auto, (max-width: 641px) 100vw, 641px\" \/><\/p>\n<p dir=\"ltr\" style=\"text-align: justify;\">Fig.5 Flame temperature of n-heptane with increasing methane blending ratio.<\/p>\n<p dir=\"ltr\" style=\"text-align: justify;\">The effect of adding 40% CH\u2084 to heptane on the calculated aromatic species profiles is compared in Fig. 6. As shown in the figure, the peak concentration of A1 shows a decrease with the addition of 40% CH<sub>4<\/sub>. The suppression effect of CH<sub>4<\/sub> addition becomes progressively more pronounced for larger PAHs (I,e A2\u2011A4). This size\u2011dependent inhibition strongly suggests that methane addition interferes with the\u00a0molecular growth processes\u00a0beyond the first aromatic ring. The chemical mechanism likely involves the perturbation of reaction sequences leading from A1 to A4, possibly through the aforementioned modification of the HACA mechanism or via the provision of additional H\u2011atoms that terminate growth [22, 24, 26, 28]. Notably, the spatial profiles of all aromatic species shift towards the fuel nozzle in tandem with the temperature profile shift, reinforcing the linkage between the altered thermal structure and the chemistry of soot precursor formation.<\/p>\n<p dir=\"ltr\" style=\"text-align: justify;\"><img loading=\"lazy\" decoding=\"async\" width=\"1280\" height=\"895\" class=\"wp-image-15537\" src=\"http:\/\/www.hnjournal.net\/wp-content\/uploads\/2025\/12\/word-image-15525-4.png\" srcset=\"https:\/\/www.hnjournal.net\/wp-content\/uploads\/2025\/12\/word-image-15525-4.png 1280w, https:\/\/www.hnjournal.net\/wp-content\/uploads\/2025\/12\/word-image-15525-4-300x210.png 300w, https:\/\/www.hnjournal.net\/wp-content\/uploads\/2025\/12\/word-image-15525-4-1024x716.png 1024w, https:\/\/www.hnjournal.net\/wp-content\/uploads\/2025\/12\/word-image-15525-4-768x537.png 768w, https:\/\/www.hnjournal.net\/wp-content\/uploads\/2025\/12\/word-image-15525-4-18x12.png 18w\" sizes=\"auto, (max-width: 1280px) 100vw, 1280px\" \/><\/p>\n<p dir=\"ltr\" style=\"text-align: justify;\">Fig.6 Benzene and PAHs formation of n-heptane with 40% of methane blending ratio. <br \/><strong>Conclusions <\/strong><\/p>\n<p dir=\"ltr\" style=\"text-align: justify;\">This numerical investigation elucidates the impact of methane addition on soot formation pathways in a laminar n-heptane diffusion flame. The coupled gas-phase and soot model demonstrated good predictive capability against experimental data for the baseline n-heptane flame. The key finding is that methane blending consistently suppresses soot formation, as quantified by the reduction in peak soot volume fraction with increasing methane doping ratio. This suppression is attributed to a combination of dilution of soot precursors from n-heptane pyrolysis and basic chemical effects. The chemical role of methane is elucidated through the analysis of flame structure and precursor formation. Although the peak flame temperature is largely unaffected, the spatial shift of the thermal field influences precursor formation zones. More significantly, methane addition inhibits the formation of larger PAHs, with the suppression effect becoming more pronounced for larger aromatic species like pyrene (A4). This trend strongly suggests that methane actively inhibits with the growth chemistry responsible for building larger PAHs, which are critical soot inception precursors. The mechanism likely involves the alteration of the HACA reaction pathway and competition for key radical species. These results indicate that methane is not only a diluent but also a chemical inhibiter that alter the reaction chain from small hydrocarbons to soot precursors.<\/p>\n<p dir=\"ltr\" style=\"text-align: justify;\"><strong>Acknowledgments<\/strong><\/p>\n<p dir=\"ltr\" style=\"text-align: justify;\">The author acknowledges the university of Sinnar for support<\/p>\n<p dir=\"ltr\" style=\"text-align: justify;\"><strong>References<\/strong><\/p>\n<p dir=\"ltr\" style=\"text-align: justify;\">[1] Korakianitis T, Namasivayam AM, Crookes RJ. Natural-gas fueled spark-ignition (SI) and compression-ignition (CI) engine performance and emissions. 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Therm Sci 2024;28(00):3967-78.<\/p>","protected":false},"excerpt":{"rendered":"<p>Introduction Increasing global challenges, including oil shortages and air pollution, have highlighted the urgent need for advanced, sustainable power transmission solutions in the transportation industry [1]. 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